Improved Voltage and Cycling for Li+ Intercalation in High‐Capacity Disordered Oxyfluoride Cathodes

نویسندگان

  • Shuhua Ren
  • Ruiyong Chen
  • Emad Maawad
  • Oleksandr Dolotko
  • Alexander A. Guda
  • Viktor Shapovalov
  • Di Wang
  • Horst Hahn
  • Maximilian Fichtner
چکیده

New high-capacity intercalation cathodes of Li2V x Cr1-x O2F with a stable disordered rock salt host framework allow a high operating voltage up to 3.5 V, good rate performance (960 Wh kg-1 at ≈1 C), and cycling stability.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Synthesis, characterization and cycling performance of novel chromium oxide cathode materials for lithium batteries

Chromium oxide (CrOx) cathode material (with chromium oxidation state of +5.3) was synthesized by thermal decomposition of chromium trioxide at high temperature and pressure in oxygen atmosphere. The duration of thermal decomposition had a significant effect on the performance of these materials in terms of lithiation capacity. The detrimental effect of CrO3 and lower oxidation state chromium o...

متن کامل

Nanoporous Ag-CNTs foamed electrode for lithium intercalation

Intercalation of lithium into Ag-CNTs sample is reported here. We have used a nano-porous silver foam as a frame for deposition of the CNTs   inside   the   pores   by   electrophoresis   deposition   (EPD) technique. By using  chronopotentiometry method,  we  have noticed that the Li storage capacity of the prepared Ag-CNTs electrode was improved  noticeably  in  comparison  with  literature. ...

متن کامل

In-Situ TEM Electrochemical Processes in Conversion-Based Li-Ion Battery Electrodes

Intercalation-based cathode materials such as LiCoO2 (~140 mAh/g) and LiFePO4 (~160 mAh/g) are predominantly used in lithium-ion batteries because they provide exceptional cycling reversibility [1]. However, these materials have low capacity as they are limited to single electron charge transfer reaction, and thus are unlikely candidates for use in electric vehicles (EVs). Conversion compounds ...

متن کامل

Two-Dimensional Titanium Carbide MXene As a Cathode Material for Hybrid Magnesium/Lithium-Ion Batteries.

As an alternative to pure lithium-ion, Li+, systems, a hybrid magnesium, Mg2+, and Li+ battery can potentially combine the high capacity, high voltage, and fast Li+ intercalation of Li-ion battery cathodes and the high capacity, low cost, and dendrite-free Mg metal anodes. Herein, we report on the use of two-dimensional titanium carbide, Ti3C2Tx (MXene), as a cathode in hybrid Mg2+/Li+ batterie...

متن کامل

High Capacity, Temperature-Stable Lithium Aluminum Manganese Oxide Cathodes for Rechargeable Batteries

Manganese oxides are of great interest as low cost and environmentally sound intercalation cathodes for rechargeable lithium batteries, but have suffered from limited capacity and instability upon cycling at the moderately high temperatures (50-70°C) encountered in many applications. Here, we show that LixAl0.05Mn0.95O2 of both the monoclinic and orthorhombic ordered rock salt structures exhibi...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:

دوره 2  شماره 

صفحات  -

تاریخ انتشار 2015